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Additive Group-Contribution Methods for Predicting Properties of Polymer Systems
Bogdanić, Grozdana
This overview presents group-contribution models for predicting properties of pure polymers, polymer/solvent and polymer/polymer mixtures. The state of art can be easily considered taking into account that polymer solutions and blends are complicated systems, with frequent occurrence of LLE in many forms (UCST, LCST, closed loop), significant effect of temperature and polymer molar mass in phase equilibrium, the free-volume effects, and other factors causing these difficulties. The choice of a suitable model depends on the actual problem and demands, especially on the following: type of mixture (solution or blend, binary or multicomponent), type of phase equilibrium (VLE, LLE, SLE), conditions (temperature, pressure, concentration), type of calculation (accuracy, speed, yes/no answer, or complete design). The performance of various models and their range of application will be discussed.
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Fluidized Bed Gasification of a Sub-Bituminous Coal, Biomass and Coal-Biomass Co-Gasification by a Gas Containing Oxygen-CO2 Mixtures
Svoboda, Karel ; Pohořelý, Michael ; Jeremiáš, Michal ; Kameníková, Petra ; Skoblia, Sergej ; Šyc, Michal ; Punčochář, Miroslav
Based on the above stated facts we concentrated in our study on FB gasification with higher concentrations of CO2 in gasification medium and on gasification of a reactive subbituminous German coal, biomass (wood) and a coal-biomass blend at temperatures between 800 oC and 900 oC. Out attention was particularly devoted to effects of CO2 concentrations and gasification temperature on producer gas heating value, energy yield, tar and BTX yields in comparison with FB gasification with steam-O2 mixtures.
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